Why does PET-CF need annealing?
Annealing converts PET-CF from amorphous to semi-crystalline · effectively a phase change rather than a stress-relaxation cycle. As-printed PET-CF cools too fast for crystallites to form, so it starts life amorphous (HDT ~70°C). The recommended 120°C / 10h anneal drives crystallisation, locking the polymer into the higher-performing semi-crystalline state · HDT more than doubles to 147.5°C, stiffness and dimensional stability increase materially, and the chemical resistance envelope improves. Without the anneal, the spec values on this page do not apply. For load-bearing or thermally-loaded parts, annealing is mandatory.
Why is PET-CF so much more anisotropic than other CF composites?
PET-CF17 has the highest anisotropy in our commodity composite range · 2.36× tensile XY/Z (65.9 / 27.9 MPa). PA12-CF is 1.48×, PA612-CF is 1.90×, PA6-GF is 1.32×. Two factors: (1) the 17% CF loading is higher than PA12-CF's 10% (more fibre to orient along extrusion direction), and (2) the rigid PET matrix doesn't carry inter-layer load as well as the more compliant nylon matrices · Z-axis strength is essentially polymer-only with minimal fibre bridging. Design every PET-CF part with the load path running along XY. Z-loaded thin walls under 2mm are the failure mode.
Is PET-CF really moisture-insensitive?
Yes · 0.53% equilibrium water absorption per the TDS V1.0 absorption curve. That's very low for a composite (PPS-CF 0.225% and PET-GF 0.32% are drier) · ~3× drier than PA12-CF (1.5%), ~4× drier than PA612-CF (2.2%), ~6× drier than PA6-GF (3.33%). PET's polar ester linkages absorb far less water than nylon amide groups. The practical result: PET-CF parts hold dimensions and properties across UK ambient humidity cycles (30-80% RH) where nylon-CF parts swell and lose stiffness. For outdoor fixtures, marine brackets, humid workshops, and parts stored for months · PET-CF is the right CF composite.
How does PET-CF compare to PA12-CF?
PET-CF wins on stiffness (5481 vs 3311 MPa Young's modulus XY · 65% stiffer), HDT (147.5 vs 131°C at 0.45 MPa), and moisture stability (0.53% vs 1.5% water absorption). PA12-CF wins on tensile strength (77 vs 65.9 MPa XY), impact toughness (Charpy notched 9.9 vs 5.1 kJ/m² · 94% tougher), anisotropy (1.48× vs 2.36×), and ductility (4% vs 2.4% elongation). For stiffness-critical dimensional fixtures in humid service, PET-CF. For impact-loaded brackets that need to absorb shock, PA12-CF.
What is the glass transition temperature of PET-CF?
Tg is 79.3°C per the manufacturer TDS V1.0 (DSC, 10°C/min). This sits between bulk PET literature (67-81°C) and the carbon-fibre-constrained value. Above Tg, amorphous regions soften · but in the annealed semi-crystalline state the crystalline regions continue to carry load up to the HDT (147.5°C at 0.45 MPa, 105°C at 1.8 MPa). For unannealed prints, do not load above 60°C. For annealed prints, the HDT figures govern service.
Does PET-CF need a heated chamber?
No heated chamber required · the TDS specifies room-temperature chamber. However, PET-CF prints with a hotter bed (70-80°C) than the PA-CF nylons (40-50°C) to manage PET's crystallisation behaviour during cooling. Standard industrial FDM hardware with a 300°C-capable hotend and hardened nozzle handles the material · no PEEK-class equipment needed.
What nozzle is needed for PET-CF?
Hardened steel or ruby. Carbon-fibre at 17 wt% destroys a brass nozzle in 1-3 print jobs. Ruby-tipped nozzles extend life to hundreds of jobs. We run hardened-steel on every CF print as standard, included in the quote · no surcharge.
Is PET-CF chemical-resistant? · 18-row compatibility table
Excellent against hydrocarbons (petrol, diesel, oils, greases), alcohols (IPA, ethanol, methanol), dilute acids, detergents, and cleaning products · PET is the bottle-grade polymer behind food and beverage packaging. Limited against strong alkalis (PET hydrolyses in hot caustic), sustained hot water above 80°C (hydrolysis), and phenols. Fails against concentrated sulphuric or nitric acid, chlorinated solvents long-term, and high-temperature steam.
| Chemical / family | Resistance | Notes |
|---|
| Petrol / gasoline | Excellent | PET fuel-rail return lines are OEM specification |
| Diesel | Excellent | Including biodiesel and E85 ethanol-blends |
| Engine oil, gear oil, hydraulic oil | Excellent | All standard service grades |
| Brake fluid (DOT 3 / 4 / 5.1 glycol) | Excellent | DOT 5 silicone also fine |
| Coolant / antifreeze (ethylene glycol) | Excellent | Including diluted service coolant |
| Methanol, ethanol, IPA | Excellent | Cleaning + assembly OK |
| Detergents, soap, weak alkalis | Good | Workshop wash-down OK · hot caustic hydrolyses |
| Sea water / saline solution | Excellent | PET marine-grade chemistry · long-term immersion OK |
| Hydrogen peroxide ≤ 6% | Excellent | Stronger H₂O₂ attacks long-term |
| Acetone | Good | PET more solvent-resistant than amorphous PETG |
| MEK, toluene, xylene | Limited | Brief contact only · long soak attacks PET |
| Strong alkalis (NaOH > 10%) | Fails | PET hydrolyses in hot caustic · alkali attack |
| Weak organic acids (acetic, citric) | Good | Cold + dilute is fine · hot conc. degrades over weeks |
| Hot water (sustained > 80°C) | Fails | Hydrolytic attack · PET hydrolyses progressively |
| Strong acids (sulphuric, HCl, nitric) | Fails | Concentrated acid attacks PET backbone |
| Chlorinated solvents long-term (TCE, DCM) | Fails | Solvent crazing + dissolution |
| Phenols | Fails | Strong PET solvent |
| High-temperature steam | Fails | Combined heat + moisture · hydrolyses repeatedly-autoclaved parts |
Ratings reflect long-term immersion / sustained exposure. Brief contact (cleaning wipes, splashes) is more forgiving. For mission-critical chemical service, request a 7-day immersion sample before committing the design.
Is PET-CF flame-retardant?
Standard PET-CF17 is rated UL94 HB at 1.5mm wall · the lowest horizontal-burn rating. For UL94 V-0 / V-2 self-certification (electrical enclosures, transportation, aerospace), step sideways to PPS-CF (V-0 at 1.5mm) or PA6-FR (flame-retardant nylon).
Is PET-CF ESD-safe?
No · standard PET-CF17 is insulative. Surface resistivity is >10¹² Ω/sq per the TDS (rated OL · overload, beyond ESD-safe range). The 17% CF loading sits below the percolation threshold (typically 25-35 wt% for PET matrices). For ESD-sensitive electronics handling jigs and PCB fixtures, use PETG-ESD or PA612-ESD (dedicated anti-static grades).
Can PET-CF be steam-autoclaved?
Short-cycle yes, repeated cycles no. 121°C steam sits above PET's Tg (79°C) but below the annealed HDT at 0.45 MPa (147.5°C). Single autoclave cycles are mechanically workable on annealed parts. However, PET hydrolyses under combined heat plus moisture, so repeated autoclave cycles progressively degrade the polymer chain. For routine repeat steam autoclave (clinical, lab), PEEK or PPSU are the correct materials. Dry-heat sterilisation, EtO, UV-C, gamma, and IPA wipe-down are all compatible with PET-CF.
What's the typical service envelope for PET-CF?
Continuous service (annealed): -20 to ~100°C (HDT 1.8 MPa is 105°C). Short-term load: up to ~147°C (HDT 0.45 MPa). Outdoor: moderate UV tolerance, better than PA-CF nylons but coat with 2K paint for multi-year exterior service. Humid environments: yes, the headline application · 0.53% water absorption means dimensional stability holds across humidity cycles. Not for steam autoclave (repeated), not for ESD service, not for flame-rated applications, not for sub-2mm thin-walled bending parts.